| 192П | Kramatorsk — Odesa-Holovna | Departure 22:54 | Travel time 12 hr 10 min | Arrival 11:04 | |
| 053П | Dnipro-Holovny — Odesa-Holovna | Departure 16:52 | Travel time 13 hr 8 min | Arrival 06:00 | |
| 059О | Kharkiv-Pas — Odesa-Holovna | Departure 22:54 | Travel time 12 hr 10 min | Arrival 11:04 | |
| 092Д | Kramatorsk — Odesa-Holovna | Departure 00:50 | Travel time 12 hr 28 min | Arrival 13:18 | |
| 052П | Zaporizhzhya 1 — Odesa-Holovna | Departure 16:52 | Travel time 13 hr 8 min | Arrival 06:00 | |
| 153П | Dnipro-Holovny — Odesa-Holovna | Departure 10:28 | Travel time 9 hr 50 min | Arrival 20:18 | |
| 153Д | Dnipro-Holovny — Odesa-Holovna | Departure 10:28 | Travel time 11 hr 40 min | Arrival 22:08 | |
| 053Д | Dnipro-Holovny — Odesa-Holovna | Departure 17:05 | Travel time 12 hr 55 min | Arrival 06:00 |
Lviv Station is the largest railway junction in western Ukraine and one of the most important stations in the country. It was opened on December 18, 1861, and is located in the historic center of Lviv. Lviv Station is an architectural monument filled with cultural heritage. The station provides easy access to other famous landmarks of the city, such as the Opera House and Rynok Square, making it a convenient starting point for tourists.
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as: