| 007Д | Kharkiv-Pas — Odesa-Holovna | Departure 04:13 | Travel time 2 hr 29 min | Arrival 06:42 | |
| 248К | Kyiv-Pasazhyrsky — Odesa-Holovna | Departure 04:56 | Travel time 3 hr 21 min | Arrival 08:17 | |
| 267Ш | Kharkiv-Pas — Odesa-Holovna | Departure 04:13 | Travel time 2 hr 29 min | Arrival 06:42 | |
| 153П | Dnipro-Holovny — Odesa-Holovna | Departure 17:24 | Travel time 2 hr 54 min | Arrival 20:18 | |
| 297О | Kharkiv-Pas — Odesa-Holovna | Departure 16:51 | Travel time 2 hr 30 min | Arrival 19:21 | |
| 297Л | Kharkiv-Pas — Odesa-Holovna | Departure 16:51 | Travel time 2 hr 30 min | Arrival 19:21 |
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as: