| 192Ш | Odesa-Holovna — Kramatorsk | Departure 18:58 | Travel time 12 hr 49 min | Arrival 07:47 | |
| 060Ш | Odesa-Holovna — Kharkiv-Pas | Departure 18:58 | Travel time 12 hr 49 min | Arrival 07:47 | |
| 092Ш | Odesa-Holovna — Kramatorsk | Departure 21:10 | Travel time 12 hr 22 min | Arrival 09:32 | |
| 054Л | Odesa-Holovna — Dnipro-Holovny | Departure 19:10 | Travel time 13 hr 16 min | Arrival 08:26 | |
| 052Ш | Odesa-Holovna — Zaporizhzhya 1 | Departure 19:10 | Travel time 13 hr 16 min | Arrival 08:26 | |
| 154Ш | Odesa-Holovna — Dnipro-Holovny | Departure 09:15 | Travel time 9 hr 33 min | Arrival 18:48 | |
| 154Л | Odesa-Holovna — Dnipro-Holovny | Departure 07:22 | Travel time 11 hr 26 min | Arrival 18:48 | |
| 054Ш | Odesa-Holovna — Dnipro-Holovny | Departure 19:10 | Travel time 13 hr 16 min | Arrival 08:26 | |
| 754П | Odesa-Holovna — Dnipro-Holovny | Departure 07:20 | Travel time 7 hr 13 min | Arrival 14:33 |
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as:
Lviv Station is the largest railway junction in western Ukraine and one of the most important stations in the country. It was opened on December 18, 1861, and is located in the historic center of Lviv. Lviv Station is an architectural monument filled with cultural heritage. The station provides easy access to other famous landmarks of the city, such as the Opera House and Rynok Square, making it a convenient starting point for tourists.