| 059О | Kharkiv-Pas — Odesa-Holovna | Departure 16:47 | Travel time 18 hr 17 min | Arrival 11:04 | |
| 007Д | Kharkiv-Pas — Odesa-Holovna | Departure 20:03 | Travel time 10 hr 39 min | Arrival 06:42 | |
| 267Ш | Kharkiv-Pas — Odesa-Holovna | Departure 19:48 | Travel time 10 hr 54 min | Arrival 06:42 | |
| 297О | Kharkiv-Pas — Odesa-Holovna | Departure 08:30 | Travel time 10 hr 51 min | Arrival 19:21 | |
| 297Л | Kharkiv-Pas — Odesa-Holovna | Departure 08:30 | Travel time 10 hr 51 min | Arrival 19:21 | |
| 007О | Kharkiv-Pas — Odesa-Holovna | Departure 15:55 | Travel time 14 hr 15 min | Arrival 06:10 | |
| 207П | Kharkiv-Pas — Odesa-Holovna | Departure 20:01 | Travel time 13 hr 28 min | Arrival 09:29 |
The Kharkiv-Passazhyrskyi station is located in the center of Kharkiv and is one of the most important railway hubs in Ukraine. It was opened in 1869 and has become a key place for passenger transportation from Kharkiv to other cities in Ukraine. The station features a spacious railway platform and provides convenient access to various modes of transport.
The Odessa-Golovna station is located in the center of Odesa, at the intersection of Prymorska Street and Hlavna Square. It was opened on August 14, 1875. The first train that departed from this station was connected to Chisinau. The Odessa-Golovna station is one of the largest and busiest stations in Ukraine. It serves passengers in many directions, including the route to Lozova. Various amenities for travelers are located near the station, such as: